china titanium dioxide anatase b101

Lithopone B301, Lithopone B311 powder, brilliant white pigment used in paints, inks, leather, paper, linoleum, and face powder. It was developed in the 1870s as a substitute or supplement for lead carbonate (white lead), to overcome its drawbacks of toxicity, poor weathering, and darkening in atmospheres that contain sulfur compounds. Lithopone B301, Lithopone B311 powder is an insoluble mixture of barium sulfate and zinc sulfide that precipitates upon mixing solutions of barium sulfide and zinc sulfate. The precipitate is recovered by filtration, then calcined (roasted) at temperatures above 600° C (1,112° F). Although Lithopone B301, Lithopone B311 powder has been replaced in many applications by titanium dioxide, it is still widely used in a number of products, such as water paints.

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titanium oxide and 2 per cent' sulphuric acidand 63 per cent water, are slowly added to a solution containing 1050 pounds of barium sulphide, held in a large cylindrical tank, provided with a rotary agitation :capable of producing rapid agitation. The mass isthus v rapidly agitated, and the 2 per cent of sulphuric acid contained in the titanium acid cake reacts with a small portion of the barium sulphide. This reaction may be represented by the following equation TiO H 80 The free sulphuric acid of the titanium acid cake is neutralized by thebarium sul-' phide solution, forming barium sulphate and hydrogen sulphide, as indicated by the above equation. As the sulphuric acid is present only in a small percentage, the major porltiion of the barium sulphide remains as suc very fine colloidal suspension. The barium sulphate produced is also very fine, and the presence of this. very fine barium sulphate in suspension, and also of the very fine colloidal titanium oxide, is believed to be the explanation of the great improvement in the properties of the finished lithopone.

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Titanium dioxide, commonly known as TiO2, is a naturally occurring oxide of titanium. Among its two primary crystal forms, rutile TiO2 is particularly valued for its high refractive index and exceptional hiding power, making it an essential component in the production of emulsion latex paints. The unique properties of rutile titanium dioxide enhance the quality and performance of latex paints, establishing its manufacturer's reputation for producing top-tier products.

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The production process within these factories is intricate and requires precise control over chemical reactions. First, the raw rutile ore is extracted from mines and then crushed into a fine powder. This powder undergoes a series of leaching processes to remove impurities. Afterward, it is subjected to the chlorination process, where it reacts with chlorine gas at high temperatures to produce titanium tetrachloride. This compound is then refined further through vapor deposition or oxidation to yield high-purity titanium dioxide.

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